(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates

(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates Full article

Journal

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Output data

Year: 2001, Volume: 627, Number: 11, Pages: 2499-2505 Pages count : DOI: 10.1002/1521-3749(200111)627:11<2499::AID-ZAAC2499>3.0.CO;2-Z

Tags

borates; polyfluoroalken-1-yl; NMR spectroscopy

Authors

Frohn HL , Bardin VV

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) NN Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

(T)he potassium fluoroborates K[RCF=CFBF3] (R = F, Cl (cis-/trans-mixture), trans-C4F9, cis-C2F5, cisC(6)F(13), trans-C4H9, trans-C6H5) were prepared by fluoridation (methoxide-fluoride substitution with K[HF2]) of RCF=CFB(OMe)(2) and Li[RCF=CFB(OMe)(3)] which were obtained from RCF=CFLi and B(OMC)(3). The K[RCF=CFBF3] salts were characterized by their H-1, B-11, F-19 NMR and IR spectra.

Frohn H. , Bardin V.
(Fluoroorgano)fluoroboranes and -fluoroborates. 2. Synthesis and spectroscopic characterization of potassium polyfluoroalken-1-yltrifluoroborates
Zeitschrift fur Anorganische und Allgemeine Chemie. 2001. V.627. N11. P.2499-2505. DOI: 10.1002/1521-3749(200111)627:11<2499::AID-ZAAC2499>3.0.CO;2-Z WOS Scopus РИНЦ

Published print:

Nov 1, 2001

Web of science	WOS:000172197000011
Scopus	2-s2.0-0035646626
Elibrary	13386728
OpenAlex	W1978860933