1,2,4,3,5-benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine

1,2,4,3,5-benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine Full article

Journal

Chemical Communications
ISSN: 1359-7345

Output data

Year: 2001, Number: 18, Pages: 1774-1775 Pages count : 2 DOI: 10.1039/b105001j

Authors

Makarov AY ¹ , Shakirov MM ¹ , Shuvaev KV ² , Bagryanskaya IY ¹ , Gatilov YV ¹ , Zibarev AV ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

Previously unknown 1,2,4,3,5-benzotrithiadiazepine 1 was prepared by 1: 1 condensation of Ph-N=S=N-SiMe3 with S2Cl2 followed by intramolecular ortho-cyclization of [Ph-N=S=N-S-S-Cl] intermediate, and hydrolyzed in pyridine to unusual macrocyclic 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine 2.

Makarov A. , Shakirov M. , Shuvaev K. , Bagryanskaya I. , Gatilov Y. , Zibarev A.
1,2,4,3,5-benzotrithiadiazepine and its unexpected hydrolysis to unusual 7H,14H-dibenzo[d,i][1,2,6,7,3,8]tetrathiadiazecine
Chemical Communications. 2001. N18. P.1774-1775. DOI: 10.1039/b105001j WOS Scopus РИНЦ

Web of science	WOS:000171287300034
Scopus	2-s2.0-0035929282
Elibrary	13373045
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