Molecular structure and properties of N,N '-disulfinyl-1,2-diaminobenzene

Molecular structure and properties of N,N '-disulfinyl-1,2-diaminobenzene Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2001, Volume: 71, Number: 7, Pages: 1050-1054 Pages count : 5 DOI: 10.1023/A:1013101604063

Authors

Bagryanskaya I.Yu. ^1,2 , Gatilov Yu.V. ^1,2 , Makarov A.Yu. ^1,2 , Shakirov M.M. ^1,2 , Shuvaev K.V. ^1,2 , Zibarev A.V. ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

According to X-ray diffraction data, N,N'-disulfinyl-1,2-diaminobenzene in crystal exists as a planar Z,Z isomer. On heating or under the action of catalytic amounts of water, as well as in reactions with LiN(SiMe3)(2) or PCl5 in 1 : 1 or 1 : 2 molar ratios it quantitatively converts into 2,1,3-benzothiadiazole. According to N-15 NMR data, this transformation is accompanied by deshielding of the nitrogen atoms by 18 ppm.

Bagryanskaya I.Y. , Gatilov Y.V. , Makarov A.Y. , Shakirov M.M. , Shuvaev K.V. , Zibarev A.V.
Molecular structure and properties of N,N '-disulfinyl-1,2-diaminobenzene
Russian Journal of General Chemistry. 2001. V.71. N7. P.1050-1054. DOI: 10.1023/A:1013101604063 WOS Scopus РИНЦ

Web of science	WOS:000173333600015
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