Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group

Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2001, Volume: 37, Number: 4, Pages: 517-522 Pages count : 6 DOI: 10.1023/A:1012429802321

Authors

Krasnov B.I. ¹ , Platonov V.E. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhstov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Perfluoroalkylbenzenes under a treatment of a system Zn(Cu)-DMF-H2O-electrolyte give rise in high yield to products of fluorine substitution by hydrogen in position 4. In perfluoro-tert-butylbenzene are substituted by hydrogen the fluorine atoms in positions 2 and 4; here the DMF-water ratio affects the regioselectivity of the process. In the perfluoro-4-tert-butyltoluene is mainly substituted the fluorine in the ortho-position to the C(CF3)(3) group.

Krasnov B.I. , Platonov V.E.
Reductive transformations of organofluorine compounds: III. Hydrodefluorination of perfluoroalkylbenzenes effected by Zn(Cu). The unusual behavior of compounds containing perfluorinated tert-butyl group
Russian Journal of Organic Chemistry. 2001. V.37. N4. P.517-522. DOI: 10.1023/A:1012429802321 WOS Scopus РИНЦ

Web of science	WOS:000170630600008
Scopus	2-s2.0-0035537141
Elibrary	13365445
OpenAlex	W2996048809