Reactions of 1-halo-4-nitroanthraquinones with C-nucleophiles

Reactions of 1-halo-4-nitroanthraquinones with C-nucleophiles Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2001, Volume: 37, Number: 3, Pages: 410-415 Pages count : 6 DOI: 10.1023/A:1012444810981

Authors

Tabatskaya A.A. ¹ , Beregovaya I.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

1-Fluoro-4-nitroanthraquinone reacts with C-nucleophiles, yielding the corresponding fluorine replacement products. Reactions of 1-chloro-4-nitroanthraquinone with the same nucleophiles result in formation of mixtures of dechlorination and denitration products whose ratio is determined by both charge and orbital interactions, Steric structure of the nucleophile can also affect the regioselectivity of substitution.

Tabatskaya A.A. , Beregovaya I.V.
Reactions of 1-halo-4-nitroanthraquinones with C-nucleophiles
Russian Journal of Organic Chemistry. 2001. V.37. N3. P.410-415. DOI: 10.1023/A:1012444810981 WOS Scopus РИНЦ

Web of science	WOS:000170448500019
Scopus	2-s2.0-0035533486
Elibrary	13382535
OpenAlex	W2999831705