Skeletal transformations of perfluoro-1-phenylindan under the action of antimony pentafluoride Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2001, Volume: 107, Number: 1, Pages: 53-57 Pages count : DOI: 10.1016/S0022-1139(00)00346-8 | ||
| Tags | skeletal transformations; perfluorophenylindan; antimony pentafluoride; NMR spectroscopy; mass spectrometry | ||
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Abstract:
Perfluoro-1 -phenylindan (1) was obtained from perfluoroindan and pentafluorobenzene in the presence of SbF5. Compound 1 heated with antimony pentafluoride at 170 degreesC and then treated with water gave a mixture of perfluorinated 9-methylfluorene (5), 9-hydroxy-9-methylfluorsne (6), 9-methyl- 1,2.3.4.5,6,7,8-octahydroanthracene (7), 1,9-dimethyl-5,6,7,8-tetrahydro-beta -naphthindan (8). When heated with SbF5 in the presence of HF and then treated with water, compound 1 is transformed to a mixture of products 5. 6, perfluoro-1.2.3.3,5,6.7,8-octahydroanthracene (9), perfluoro-10-methyl-9(10H)anthracenone (10) and 10-H-perfluoro-10-methyl-9(10H)anthracenone (11). (C) 2001 Elsevier Science B.V. All rights: reserved.
Cite:
Karpov V.
, Mezhenkova T.
, Platonov V.
, Sinyakov V.
Skeletal transformations of perfluoro-1-phenylindan under the action of antimony pentafluoride
Journal of Fluorine Chemistry. 2001. V.107. N1. P.53-57. DOI: 10.1016/S0022-1139(00)00346-8 WOS Scopus РИНЦ
Skeletal transformations of perfluoro-1-phenylindan under the action of antimony pentafluoride
Journal of Fluorine Chemistry. 2001. V.107. N1. P.53-57. DOI: 10.1016/S0022-1139(00)00346-8 WOS Scopus РИНЦ
Dates:
| Published print: | Jan 1, 2001 |
Identifiers:
| Web of science | WOS:000166676200009 |
| Scopus | 2-s2.0-0035176155 |
| Elibrary | 13375640 |
| OpenAlex | W2094604928 |