Dimethyl- and diethyltin(IV) compounds with perfluorobiphenyl-4-thiolate and perfluoronaphthalene-2-thiolate anions: The crystal structure of (CH3)(2)Sn(C12F9S)(2)

Dimethyl- and diethyltin(IV) compounds with perfluorobiphenyl-4-thiolate and perfluoronaphthalene-2-thiolate anions: The crystal structure of (CH3)(2)Sn(C12F9S)(2) Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2000, Volume: 26, Number: 12, Pages: 861-865 Pages count : 5 DOI: 10.1023/A:1026627024967

Authors

Larionov SV , Leonova TG , Glinskaya LA , Klevtsova RF , Platonov VE , Maksimov AM , Fadeeva VP , Batrachenko NI

Affiliations

1	(Данные Web of science) Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Compounds (CH3)(2)Sn(C12F9S)(2) (I), (CH3)(2)Sn(C10F7S)(2) (II), and (C2H5)(2)Sn(C10F7S)(2) (III) were synthesized. Single crystals of I were grown and structurally characterized using X-ray diffraction analysis (1590 reflections, R = 0.0209). The crystals are orthorhombic, a = 40.848(8) Angstrom, b = 6.058(1) Angstrom, c = 11.183(2) Angstrom, V = 2767(1) Angstrom (3), rho (calcd.) = 2.024 g/cm(3), space group Pbcn, Z = 4. The structure is built from monomeric molecules. The coordination polyhedron of the Sn atom (the SnC2S2 core) is a distorted tetrahedron. Compounds I-III are volatile when heated in vacuo. Thermolysis of these compounds results in SnO2 (in air) or SnS2 (in argon).

Larionov S. , Leonova T. , Glinskaya L. , Klevtsova R. , Platonov V. , Maksimov A. , Fadeeva V. , Batrachenko N.
Dimethyl- and diethyltin(IV) compounds with perfluorobiphenyl-4-thiolate and perfluoronaphthalene-2-thiolate anions: The crystal structure of (CH3)(2)Sn(C12F9S)(2)
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2000. V.26. N12. P.861-865. DOI: 10.1023/A:1026627024967 WOS Scopus РИНЦ

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