Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR

Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR Full article

Journal

Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169

Output data

Year: 2000, Volume: 158, Number: 1, Pages: 377-380 Pages count : DOI: 10.1016/S1381-1169(00)00108-4

Tags

ZSM-5; alkanes; N2O; relative reactivity; NMR

Authors

Vereshchagin SN , Kirik NP , Shishkina NN , Morozov SV , Shakirov MM , Mamatyuk VI , Anshits AG

Affiliations

1	(Данные Web of science) RAS, SB, Inst Chem & Chem Engn, Krasnoyarsk 660049, Russia
2	(Данные Web of science) RAS, SB, Inst Organ Chem, Novosibirsk, Russia

Oxidative conversion of methane, ethane, propane, benzene, hydrogen and their binary mixtures R1-R2-N2O-He (where R1, R2 are substances under study) were studied on HZSM-5 at 350-450 degrees C. Relative reactivities were estimated, rate of conversion of hydrocarbons correlating with the strength of C-H bond. C-13 label distribution in the product of (CH4)-C-13-C6H6-N2O feed was studied by GC-MS, H-1 and C-13 NMR. It was shown that methane was capable to alkylate the aromatic ring under reaction condition, giving toluene and xylenes from benzene. (C) 2000 Elsevier Science B.V. All rights reserved.

Vereshchagin S. , Kirik N. , Shishkina N. , Morozov S. , Shakirov M. , Mamatyuk V. , Anshits A.
Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and C-13 NMR
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.377-380. DOI: 10.1016/S1381-1169(00)00108-4 WOS Scopus РИНЦ

Published print:

Sep 1, 2000

Web of science	WOS:000089201200051
Scopus	2-s2.0-0034622697
Elibrary	13347808
OpenAlex	W1987904439