Reactions of aromatic compounds with nucleophilic reagents in liquid ammonia: XVII. Effect of ionic association on the orientation in aryloxydefluorination of 2,4-difluoronitrobenzene

Reactions of aromatic compounds with nucleophilic reagents in liquid ammonia: XVII. Effect of ionic association on the orientation in aryloxydefluorination of 2,4-difluoronitrobenzene Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2000, Volume: 36, Number: 6, Pages: 801-807 Pages count : 7 DOI: 10.1007/BF02757434

Authors

Politanskaya L.V. ¹ , Ryabitskaya E.V. ¹ , Malykhin E.V. ¹ , Steingartz V.D. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Div, Novosibirsk 630090, Russia

The analysis of dependence of fluorine replacement orientation in 2,4-difluoronitrobenzene effected by nucleophiles Y-C6H4OM (Y = p-OMe, p-Me, m-Me, H, p-F, p-Cl, m-F, m-Cl; M = Li, Na, K, Et4N, Bu4N) in liquid ammonia medium at -35 degreesC on the nature of M, Y, on nucleophile concentration, on addition of crown ethers, diaminoalkanes, and dimethoxyethane indicates the occurrence of ionic association at M = K, Na.

Politanskaya L.V. , Ryabitskaya E.V. , Malykhin E.V. , Steingartz V.D.
Reactions of aromatic compounds with nucleophilic reagents in liquid ammonia: XVII. Effect of ionic association on the orientation in aryloxydefluorination of 2,4-difluoronitrobenzene
Russian Journal of Organic Chemistry. 2000. V.36. N6. P.801-807. DOI: 10.1007/BF02757434 WOS Scopus РИНЦ

Published print:

Jun 1, 2000

Web of science	WOS:000166138500008
Scopus	2-s2.0-0034195132
Elibrary	13338463
OpenAlex	W2021997928