Perfluorozinc aromatics by direct insertion of zinc into C-F or C-Cl bonds

Perfluorozinc aromatics by direct insertion of zinc into C-F or C-Cl bonds Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039

Output data

Year: 2000, Volume: 41, Number: 20, Pages: 3817-3819 Pages count : 3 DOI: 10.1016/S0040-4039(00)00527-X

Authors

Miller Alexey O. ¹ , Krasnov Vyacheslav I. ² , Peters Dietmar ¹ , Platonov Vyacheslav E. ² , Miethchen Ralf ¹

Affiliations

1	University of Rostock, Department of Chemistry, Buchbinderstr. 9, D-18051 Rostock, Germany
2	N.N. Vorozhtsov Institute of Organic Chemistry Siberian Division of Russian Academy of Sciences, Lavrentiev Ave. 9, 630090 Novosibirsk, Russia

For the first time perfluoroaromatic organozinc compounds were obtained by direct action of zinc on C-F bonds in the presence of metal salts (SnCl2, CuCl2, ZnBr2). The reactions are accelerated by ultrasound. The scope of the method can be extended to polyfluoroaromatics which contain other halogen atoms (Cl) in the aromatic ring. (C) 2000 Elsevier Science Ltd. All rights reserved.

Miller A.O. , Krasnov V.I. , Peters D. , Platonov V.E. , Miethchen R.
Perfluorozinc aromatics by direct insertion of zinc into C-F or C-Cl bonds
Tetrahedron Letters. 2000. V.41. N20. P.3817-3819. DOI: 10.1016/S0040-4039(00)00527-X WOS Scopus

Published print:

May 1, 2000

Web of science	WOS:000087274400013
Scopus	2-s2.0-0034697456
OpenAlex	W2006503677