Intramolecular borylation reaction catalyzed by Lewis acid: preparation of 1H-2,1-benzazaborole derivatives

Intramolecular borylation reaction catalyzed by Lewis acid: preparation of 1H-2,1-benzazaborole derivatives Full article

Journal

Chemical Communications
ISSN: 1359-7345

Output data

Year: 2000, Number: 17, Pages: 1587-1588 Pages count : 2 DOI: 10.1039/b003999n

Authors

Genaev Alexander M. ¹ , Nagy Sandor M. ² , Salnikov Georgii E. ¹ , Shubin Vyacheslav G. ¹

Affiliations

1	(Данные Web of science) Equistar Chem LP, Equistar Technol Ctr, Cincinnati, OH USA
2	(Данные Web of science) Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Div, Novosibirsk 630090, Russia

It has been found that 1H-2,1-benzazaboroles can be prepared by the interaction of substituted benzylaminochloroboranes with Al2Cl6 in CH2Cl2 at 0 degrees C, the C-13 NMR spectroscopy data obtained being in favour of an electrophilic substitution mechanism involving formation of cationic complexes as reactive intermediates.

Genaev A.M. , Nagy S.M. , Salnikov G.E. , Shubin V.G.
Intramolecular borylation reaction catalyzed by Lewis acid: preparation of 1H-2,1-benzazaborole derivatives
Chemical Communications. 2000. N17. P.1587-1588. DOI: 10.1039/b003999n WOS Scopus РИНЦ

Web of science	WOS:000088914800014
Scopus	2-s2.0-0034618619
Elibrary	931092
OpenAlex	W1991289158