Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br)

Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br) Full article

Journal

Journal of Organometallic Chemistry
ISSN: 0022-328X

Output data

Year: 1998, Volume: 570, Number: 2, Pages: 255-263 Pages count : 9 DOI: 10.1016/S0022-328X(98)00805-5

Tags

silanes; electrophilic substitution

Authors

Frohn H.J. ¹ , Lewin A. ¹ , Bardin V.V. ²

Affiliations

1	Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universität Duisburg, Lotharstrasse 1, D-47048 Duisburg, Germany
2	Institute of Organic Chemistry, 630090 Novosibirsk, Russia

Halogeno(methyl)pentafluorophenylsilanes C6F5SiMenX3-n (n = 1, 2) (X = F, Cl, Br) were prepared in good yields from the corresponding phenylsilanes C6F5SiMenPh3-n by reactions with the electrophiles aHF, HCl-AlCl3, Br-2-AlBr3 or AlX3 (X = Cl, Br) halogenated hydrocarbons. Additionally, reactions of C6F5SiMe3 and (C6F5)(2)SiMe2 with selected electrophiles were studied. (C) 1998 Elsevier Science S.A. All rights reserved.

Frohn H.J. , Lewin A. , Bardin V.V.
Reactions of methyl(pentafluorophenyl)- and methyl(pentafluorophenyl)phenylsilanes with electrophiles. A convenient preparative route to halogeno(methyl)pentafluorophenylsilanes C6F5SiMe2X and C6F5SiMeX2 (X = F, Cl and Br)
Journal of Organometallic Chemistry. 1998. V.570. N2. P.255-263. DOI: 10.1016/S0022-328X(98)00805-5 WOS Scopus РИНЦ

Published print:

Nov 1, 1998

Web of science	WOS:000076724200012
Scopus	2-s2.0-0011873437
Elibrary	13279795
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