Photochemical and thermal rearrangements of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones

Photochemical and thermal rearrangements of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1998, Volume: 47, Number: 12, Pages: 2437-2440 Pages count : 4 DOI: 10.1007/BF02641550

Tags

photochemistry; Smiles rearrangement; 1-(4-tert-butylphenoxy)-2-(p-toluidino)-9,10-anthraquinone; 2-(p-anisidino)-1-(4-tert-butylphenoxy)-9; 10-anthraquinone

Authors

Mainagashev I.Ya. ¹ , Klimenko L.S. ¹ , Gritsan N.P. ²

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation
2	Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

Photochemical transformations of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones involve migration of the tert-butylphenyl group either to the peri-located carbonyl oxygen to give 2-arylamino-9-(4-tert-butylphenoxy)-1,10-anthraquinones or to the nitrogen atom to give 2-aryl(4-tert-butylphenyl)amino-1-hydroxy-9,10-anthraquinones (typical products of the Smiles rearrangement).

Mainagashev I.Y. , Klimenko L.S. , Gritsan N.P.
Photochemical and thermal rearrangements of 2-arylamino-1-(4-tert-butylphenoxy)-9,10-anthraquinones
Russian Chemical Bulletin. 1998. V.47. N12. P.2437-2440. DOI: 10.1007/BF02641550 WOS Scopus РИНЦ

Published print:

Dec 1, 1998

Web of science	WOS:000079263800021
Scopus	2-s2.0-0032244113
Elibrary	13280090
OpenAlex	W2952322746