Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O.

Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O. Full article

Journal

Tetrahedron
ISSN: 0040-4020

Output data

Year: 1997, Volume: 53, Number: 5, Pages: 1797-1812 Pages count : 16 DOI: 10.1016/S0040-4020(96)01090-3

Authors

Krasnov V.I. ¹ , Platonov V.E. ¹ , Beregovaya I.V. ¹ , Shchegoleva L.N. ¹

Affiliations

1	Institute of Organic Chemistry, Novosibirsk, 630090, Russia

Perfluorinated xylenes and perfluoro-para-cymene undergo hydrodefluorination under the action of Zn(Cu)-DMF-H2O. Hydrogen enters mainly at the benzyl position of para-dialkylbenzenes and at the para position to perfluoroalkyl groups of perfluorinated ortho- and meta-xylenes. The process presumably involves radical anions as intermediates. A product of perfluoro-4-methylbenzyl radical trapping by hexene-1 was obtained Quantum-chemical calculations of radical anions of the compounds under investigation have been carried out. (C) 1997, Elsevier Science Ltd.

Krasnov V.I. , Platonov V.E. , Beregovaya I.V. , Shchegoleva L.N.
Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O.
Tetrahedron. 1997. V.53. N5. P.1797-1812. DOI: 10.1016/S0040-4020(96)01090-3 WOS Scopus РИНЦ

Published print:

Feb 1, 1997

Web of science	WOS:A1997WF28300027
Scopus	2-s2.0-0031550585
Elibrary	13259657
OpenAlex	W1967221220