FTIR spectra of matrix isolated 2-methylbenzonorbornen-2-yl-type cations

FTIR spectra of matrix isolated 2-methylbenzonorbornen-2-yl-type cations Full article

Journal

Journal of the Chemical Society. Perkin Transactions 2
ISSN: 0300-9580

Output data

Year: 1997, Number: 4, Pages: 667-668 Pages count : 2 DOI: 10.1039/a607105h

Authors

Vancik H. ¹ , Genaev A.M. ² , Shubin V.G. ²

Affiliations

1	Department of Chemistry, Faculty of Science, University of Zagreb, 41000 Zagreb
2	Novosibirsk Inst. of Organ. Chem., Siberian Div. Russ. Acad. of Sci., Novosibirsk 630090

FTIR spectra suggest that ionization of 2-exo-chloro-2-methylbenzonorbornene dagger in an SbF5 matrix at -196 degrees C leads to 2-methyl-2-benzonortricyclyl cation which rearranges into a partially pi-bridged 2-methyibenzonorbornen-2-ylion at -123 degrees C.

Vancik H. , Genaev A.M. , Shubin V.G.
FTIR spectra of matrix isolated 2-methylbenzonorbornen-2-yl-type cations
Journal of the Chemical Society. Perkin Transactions 2. 1997. N4. P.667-668. DOI: 10.1039/a607105h WOS Scopus РИНЦ

Web of science	WOS:A1997WU62000003
Scopus	2-s2.0-0041021289
Elibrary	13259768
OpenAlex	W2093094219