Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane

Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1997, Volume: 46, Number: 4, Pages: 780-785 Pages count : 6 DOI: 10.1007/BF02495213

Tags

halogenotetrafluorobenzenes; dihalogenotetrafluorobenzenes; tris(diethylamino)phosphine; silyldehalogenation; silyldeprotonation

Authors

Bardin V.V. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch on the Russian Academy of Sciences, 9 ul. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

The rate of replacement of the halogen atom in isomers of RC6F4X (X = Cl, Br, or I) by the SiMe3 group under the action of Me3SiCl and P(NEt2)(3) depends on the nature and the mutual arrangement of the substituents X and R. In addition to silyldehalogenation, compounds C6HF4X (X = Br or I) undergo silyldeprotonation and reduction to tetrafluorobenzenes.

Bardin V.V.
Reactions of polyfluoroaromatic compounds with electrophilic agents in the presence of tris(dialkylamino)phosphine .6. Reactions of halogenotetrafluorobenzenes RC6F4X (X=Cl, Br, or I) with chlorotrimethylsilane
Russian Chemical Bulletin. 1997. V.46. N4. P.780-785. DOI: 10.1007/BF02495213 WOS Scopus РИНЦ

Published print:

Apr 1, 1997

Web of science	WOS:A1997XN59600029
Scopus	2-s2.0-0031527418
Elibrary	13251295
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