Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates

Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2020, Volume: 90, Number: 1, Pages: 50-61 Pages count : DOI: 10.1134/S1070363220010089

Tags

aryldihaloboranes; aryltrifluoroborates; boron halides; aluminum halides

Authors

Bardin V. V. ¹ , Prikhod'ko S. A. ² , Shmakov M. M. ² , Shabalin A. Yu. ² , Adonin N. Yu. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Fed Res Ctr, Novosibirsk 630090, Russia

Fluorine-containing aryldihalogenoboranes have been obtained by the reaction of boron and aluminum chlorides and bromides with potassium aryltrifluoroborates K[ArBF3] under mild conditions. In a similar way, bis(pentafluorophenyl)halogenoboranes have been synthesized by the reaction with K[(C6F5)(2)BF2]. The reaction of K[C6F5BF3] with AlBr3 affords a mixture of C6F5BF2 and C6F5BCl2 due to fast conversion of AlBr3 to AlBrCl2. The inductive and resonance parameters of BCl2 and BBr2 groups were calculated.

Bardin V.V. , Prikhod'ko S.A. , Shmakov M.M. , Shabalin A.Y. , Adonin N.Y.
Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates
Russian Journal of General Chemistry. 2020. V.90. N1. P.50-61. DOI: 10.1134/S1070363220010089 WOS Scopus РИНЦ

Бардин В.В. , Приходько С.А. , Шмаков М.М. , Шабалин А.Ю. , Адонин Н.Ю.
СИНТЕЗ ФТОРСОДЕРЖАЩИХ АРИЛ(ГАЛОГЕН)БОРАНОВ ИЗ АРИЛ(ФТОР)БОРАТОВ КАЛИЯ
Журнал общей химии (RUSS J GEN CHEM+). 2010. Т.90. №1. С.72-84. DOI: 10.31857/S0044460X20010096 РИНЦ

Published print:	Jan 1, 2020
Published online:	Mar 26, 2020

Web of science	WOS:000521739700008
Scopus	2-s2.0-85082666616
Elibrary	43263503
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