Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid

Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1996, Volume: 45, Number: 2, Pages: 381-383 Pages count : 3 DOI: 10.1007/BF01433977

Tags

ethyl cation; 5H-dibenzo[a,d]cycloheptene; 5H-dibenzo[a,d]cycloheptenylium cation; fragmentation; superacid

Authors

Osadchii S.A. ¹ , Stanescu M.D. ² , Mamatyuk V.I. ¹ , Shubin V.G. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 7 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russia
2	Department of Organic Chemistry, Bucharest Polytechnic Institute, 76206, Bucharest, Romania

The 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation generated under ''long life'' conditions undergoes fragmentation to afford 5H-dibenzo[a,d]cycloheptenyl- and methylphenylhydroxycarbinyl cations but does not undergo carbocationic cyclization.

Osadchii S.A. , Stanescu M.D. , Mamatyuk V.I. , Shubin V.G.
Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid
Russian Chemical Bulletin. 1996. V.45. N2. P.381-383. DOI: 10.1007/BF01433977 WOS Scopus РИНЦ

Published print:

Feb 1, 1996

Web of science	WOS:A1996UN33000021
Scopus	2-s2.0-25444496423
Elibrary	13239315
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