Contraction of the six-membered alicyclic ring of perfluorinated ethyl- and diethyl-tetralins to five- and four-membered ones under the action of antimony pentafluoride

Contraction of the six-membered alicyclic ring of perfluorinated ethyl- and diethyl-tetralins to five- and four-membered ones under the action of antimony pentafluoride Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 1996, Volume: 77, Number: 1, Pages: 101-103 Pages count : 3 DOI: 10.1016/0022-1139(95)03383-1

Tags

alicycle contraction; perfluorinated ethyltetralins; perfluorinated diethyltetralins; antimony pentafluoride; NMR spectroscopy

Authors

Karpov V.M. ¹ , Mezhenkova T.V. ¹ , Platonov V.E. ¹

Affiliations

1	Institute of Organic Chemistry, 630090 Novosibirsk, Russia

Interaction of perfluoro-1-ethyltetralin (2) with SbF5 leads to the formation of perfluorinated 5-ethyltetralin (5), 3-methyl-4-ethylindan (6) and 1,3,4-trimethylindan (4). Perfluoro-1,4-diethyltetralin (3) under the action of SbF5 gives perfluorinated 5,8-diethyltetralin (8), 1-methyl-4,7-diethylindan (9) and 1,1-dimethyl-3,6-diethylbenzocyclobutene (10).

Karpov V.M. , Mezhenkova T.V. , Platonov V.E.
Contraction of the six-membered alicyclic ring of perfluorinated ethyl- and diethyl-tetralins to five- and four-membered ones under the action of antimony pentafluoride
Journal of Fluorine Chemistry. 1996. V.77. N1. P.101-103. DOI: 10.1016/0022-1139(95)03383-1 WOS Scopus РИНЦ

Published print:

Mar 1, 1996

Web of science	WOS:A1996UP38200017
Scopus	2-s2.0-0030097425
Elibrary	13245427
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