Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X

Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X Full article

Journal

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776

Output data

Year: 1996, Volume: 51, Number: 7, Pages: 1015-1021 Pages count : 7 DOI: 10.1515/znb-1996-0718

Tags

xenon difluoride; electrophilic oxygenation; polyfluorobenzenes; polyfluorinated 1,4-cyclohexadienones; epoxidation

Authors

Frohn H.J. ¹ , Bardin V.V. ²

Affiliations

1	Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universität Duisburg, Lotharstr. 1, D-47048 Duisburg, Germany
2	Institute of Organic Chemistry, Russian Academy of Sciences, 630090 Novosibirsk, Russia

Electrophilic oxygenation of polyfluorobenzenes C6F5 X (X = F, Cl, Br, H, CF3, NH3+, NMe(3)(+), OH and OCH2CF3) with XeF2 and H2O in HF leads to the formation of polyfluorinated 1,4-cyclohexadienones. Pentafluoroiodobenzene is converted into C6F5IF2 and C6F5IF4, whereas [C6F5N2](+) [NbF6](-) is unreactive towards this new type of electrophilic oxygenation.

Frohn H.J. , Bardin V.V.
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride .2. Electrophilic oxygenation of pentafluorobenzene derivatives C(6)F(5)X
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1015-1021. DOI: 10.1515/znb-1996-0718 WOS Scopus

Published print:	Jul 1, 1996
Published online:	Jun 2, 2014

Web of science	WOS:A1996VB44700018
Scopus	2-s2.0-0040749720
OpenAlex	W2081992410