Low-temperature hydrodechlorination of 2,3-dichlorodibenzo-p-dioxin and chlorobenzene with hydrides catalyzed by transition metal compounds

Low-temperature hydrodechlorination of 2,3-dichlorodibenzo-p-dioxin and chlorobenzene with hydrides catalyzed by transition metal compounds Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1996, Volume: 45, Number: 6, Pages: 1321-1324 Pages count : 4 DOI: 10.1007/BF01434205

Tags

hydrodechlorination; hydrides; supported catalysts; chlorobenzene; chlorinated dioxins

Authors

Simagina V.I. ¹ , Litvak V.V. ² , Stoyanova I.V. ¹ , Yakovlev V.A. ¹ , Mastikhin V.M. ¹ , Afanasenkova I.V. ² , Likholobov V.A. ¹

Affiliations

1	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prose. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

Hydrodechlorination of chlorobenzene by chemically bound hydrogen in the presence of transition metal compounds was studied. Alkali and alkaline earth metal hydrides (NaH, MgH2, LiAlH4, NnH(LiAlH4)(1/2)) were used as the sources of the chemically bound hydrogen. The effect of the natures of the hydride and of the transition metal on the activity was studied under comparable conditions. The Pd/C-NaH(LiAlH4)(1/2) catalytic systetn was found to be the most active. This system made it possible to perform the quantitative dechlorination of 2.3-dichlorodibenzo-p-dioxin at 70 degrees C.

Simagina V.I. , Litvak V.V. , Stoyanova I.V. , Yakovlev V.A. , Mastikhin V.M. , Afanasenkova I.V. , Likholobov V.A.
Low-temperature hydrodechlorination of 2,3-dichlorodibenzo-p-dioxin and chlorobenzene with hydrides catalyzed by transition metal compounds
Russian Chemical Bulletin. 1996. V.45. N6. P.1321-1324. DOI: 10.1007/BF01434205 WOS Scopus РИНЦ

Симагина В.И. , Литвак В.В. , Стоянова И.В. , Яковлев В.А. , Мастихин В.М. , Афанасенкова И.В. , Лихолобов В.А.
КАТАЛИЗИРУЕМОЕ СОЕДИНЕНИЯМИ ПЕРЕХОДНЫХ МЕТАЛЛОВ НИЗКОТЕМПЕРАТУРНОЕ ГИДРОДЕХЛОРИРОВАНИЕ 2,3-ДИХЛОРДИБЕНЗО-N-ДИОКСИНА И ХЛОРБЕНЗОЛА ГИДРИДАМИ
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 1996. №6. С.1391-1394. РИНЦ

Published print:

Jun 1, 1996

Web of science	WOS:A1996VK10500011
Scopus	2-s2.0-27844583686
Elibrary	13248151
OpenAlex	W1965838947