EVIDENCE FOR THE TRANSITION FROM S-N TO ET MECHANISM IN THE REACTION OF ARENE RADICAL-ANION WITH ALKYL HALIDE EVOKED BY THE INTRODUCTION OF AN ELECTRON-WITHDRAWING SUBSTITUENT INTO RADICAL-ANION

EVIDENCE FOR THE TRANSITION FROM S-N TO ET MECHANISM IN THE REACTION OF ARENE RADICAL-ANION WITH ALKYL HALIDE EVOKED BY THE INTRODUCTION OF AN ELECTRON-WITHDRAWING SUBSTITUENT INTO RADICAL-ANION Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039

Output data

Year: 1995, Volume: 36, Number: 46, Pages: 8465-8466 Pages count : 2 DOI: 10.1016/0040-4039(95)01685-B

Authors

Panteleeva E.V. ¹ , Vaganova T.A. ¹ , Shteingarts V.D. ¹ , Bilkis I.I. ¹

Affiliations

1	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences

The interaction of potassium salts of benzonitrile and 1,4-dicyanobenzene radical anions with cyclopropylmethyl bromide provides benzylcyclopropane, in the first case, and 4-alkyl- benzonitriles together with 2-alkyl-1,4-dicyanobenzenes containing both cyclopropylmethyl and it's isomeric 3-butenyl fragment, in the second case. These results provide evidence for the change of reaction mechanism from S-N to ET.

Panteleeva E.V. , Vaganova T.A. , Shteingarts V.D. , Bilkis I.I.
EVIDENCE FOR THE TRANSITION FROM S-N TO ET MECHANISM IN THE REACTION OF ARENE RADICAL-ANION WITH ALKYL HALIDE EVOKED BY THE INTRODUCTION OF AN ELECTRON-WITHDRAWING SUBSTITUENT INTO RADICAL-ANION
Tetrahedron Letters. 1995. V.36. N46. P.8465-8466. DOI: 10.1016/0040-4039(95)01685-B WOS Scopus

Published print:

Nov 1, 1995

Web of science	WOS:A1995TD81600032
Scopus	2-s2.0-0028837698
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