ELECTROCHEMICAL OXIDATIVE METHOXYLATION OF 4H-IMIDAZOLE 1,3-DIOXIDES TO GIVE ALPHA-METHOXY SUBSTITUTED NITROXYL RADICALS

ELECTROCHEMICAL OXIDATIVE METHOXYLATION OF 4H-IMIDAZOLE 1,3-DIOXIDES TO GIVE ALPHA-METHOXY SUBSTITUTED NITROXYL RADICALS Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1994, Volume: 43, Number: 3, Pages: 428-430 Pages count : 3 DOI: 10.1007/BF01169721

Tags

ANODIC METHOXYLATION; 4H-IMIDAZOLE 1,3-DIOXIDES; ELECTROCHEMICAL SYNTHESIS; NITROXYL RADICALS

Authors

Kursakina I.G. ¹ , Starichenko V.F. ¹ , Grigorev I.A. ¹

Affiliations

1	Siberian Branch of the Russian Academy of Sciences, Novosibirsk Institute of Organic Chemistry, 9 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

Electrochemical methoxylation of substituted 4H-imidazole 1,3-dioxides has been carried out for the first time. Nitroxyl radicals of the 2- and 3-imidazoline series with methoxy groups at the n-carbon atom of the radical site were synthesized. The yields and ratios of the electrochemical methoxylation products are close to those observed in the chemical methoxylation carried out with PbO2 and MnO2 as oxidants.

Kursakina I.G. , Starichenko V.F. , Grigorev I.A.
ELECTROCHEMICAL OXIDATIVE METHOXYLATION OF 4H-IMIDAZOLE 1,3-DIOXIDES TO GIVE ALPHA-METHOXY SUBSTITUTED NITROXYL RADICALS
Russian Chemical Bulletin. 1994. V.43. N3. P.428-430. DOI: 10.1007/BF01169721 WOS Scopus РИНЦ

Published print:

Mar 1, 1994

Web of science	WOS:A1994QA80900021
Scopus	2-s2.0-0141620121
Elibrary	31142949
OpenAlex	W2952963848