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Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example Full article

Journal Journal of Polymer Science, Part A: Polymer Chemistry
ISSN: 0887-624X , E-ISSN: 1099-0518
Output data Year: 2018, Volume: 56, Number: 23, Pages: 2656-2664 Pages count : 9 DOI: 10.1002/pola.29249
Tags kinetics of polymerization; nitroxide; stable organic radical; triarylmethyl radical
Authors Edeleva Mariya V. 1,2 , Marque Sylvain R.A. 3 , Rogozhnikova Olga Yu. 1,2 , Tormyshev Victor M. 1,2 , Troitskaya Tatiana I. 1 , Bagryanskaya Elena G. 1,2
Affiliations
1 (Данные Web of science) RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem SB, Pr Lavrentjeva 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia
3 (Данные Web of science) Aix Marseille Univ, CNRS, UMR 7273, ICR, Case 551,Ave Escadrille Normandie Niemen, F-13397 Marseille 20, France

Abstract: Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal. (c) 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 2656-2664
Cite: Edeleva M.V. , Marque S.R.A. , Rogozhnikova O.Y. , Tormyshev V.M. , Troitskaya T.I. , Bagryanskaya E.G.
Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example
Journal of Polymer Science, Part A: Polymer Chemistry. 2018. V.56. N23. P.2656-2664. DOI: 10.1002/pola.29249 WOS Scopus РИНЦ
Dates:
Published online: Oct 18, 2018
Published print: Dec 1, 2018
Identifiers:
Web of science WOS:000449661700006
Scopus 2-s2.0-85055275756
Elibrary 38645384
OpenAlex W2896247624
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