SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES

SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 1993, Volume: 63, Number: 3, Pages: 243-251 Pages count : 9 DOI: 10.1016/S0022-1139(00)80568-0

Authors

Kovtonyuk V.N. ¹ , Kobrina L.S. ¹

Affiliations

1	Institute of Organic Chemistry, Novosibirsk 630090 Russian Federation

Reactions of salts of pentafluorophenol and heptafluoronaphthols with lead aryl acetates have led to the formation of arylcyclohexadienones with an ortho-quinoid structure. The arylation of sodium pentafluorophenoxide and heptafluoro-2-naphthoxide is accompanied by nucleophilic substitution of fluorine at a double bond by pentafluorophenoxy and heptafluoro-2-naphthoxy groups, respectively. Reduction of the resulting arylcyclohexadienones gave polyfluorinated phenols and naphthols with aryl and hydroxy groups in the 1,2-position.

Kovtonyuk V.N. , Kobrina L.S.
SELECTIVE ORTHO-ARYLATION OF POLYFLUORINATED HYDROXYAROMATIC COMPOUNDS WITH LEAD ARYL ACETATES
Journal of Fluorine Chemistry. 1993. V.63. N3. P.243-251. DOI: 10.1016/S0022-1139(00)80568-0 WOS Scopus

Published print:

Aug 1, 1993

Web of science	WOS:A1993LP18800007
Scopus	2-s2.0-0010775564
OpenAlex	W2005980715