FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF

FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 1993, Volume: 65, Number: 1-2, Pages: 29-35 Pages count : 7 DOI: 10.1016/S0022-1139(00)80469-8

Authors

Chuikov I.P. ¹ , Karpov V.M. ¹ , Platonov V.E. ¹ , Beregovaya I.V. ¹ , Shchegoleva L.N. ¹

Affiliations

1	Institute of Organic Chemistry Novosibirsk 630090 Russian Federation

The reaction of perfluorinated 3-methyl-indene and 1-methylene-indan with nitrating agents in anhydrous HF leads to the formation of perfluoro-indan containing an oxygen function together with nitrofluorination products. From an analysis of the experimental data and the results of MNDO calculations of the starting compounds (including perfluorinated indene and 2-methyl-indene), their radical cations and polyfluorinated nitro-indanyl cations, a scheme for the process has been suggested including both a classical electrophilic route and a route involving radical cations of the substrates. The latter are assumed to be generated together with NO2. from the intermediate nitro-indanyl cations.

Chuikov I.P. , Karpov V.M. , Platonov V.E. , Beregovaya I.V. , Shchegoleva L.N.
FLUORO-INDENES .14. INTERACTION OF PERFLUORINATED 3-METHYLINDENE AND 1-METHYLENE-INDAN WITH NITRATING AGENTS IN ANHYDROUS HF
Journal of Fluorine Chemistry. 1993. V.65. N1-2. P.29-35. DOI: 10.1016/S0022-1139(00)80469-8 WOS Scopus

Published print:

Nov 1, 1993

Web of science	WOS:A1993MK67700007
Scopus	2-s2.0-0008560148
OpenAlex	W2028626859