EFFECT OF MEDIUM ON THE EQUILIBRIUM OF CATIONIC SIGMA-COMPLEXES AND PI-COMPLEXES - INTERCONVERSION OF 1-PENTAFLUOROPHENYLTHIO-1,2-DIMETHYL-ACENAPHTHYLENIUM AND 1,2-DIMETHYLACENAPHTHYLENE-1,2-S-PENTAFLUOROPHENYLEPISULPHONIUM IONS

EFFECT OF MEDIUM ON THE EQUILIBRIUM OF CATIONIC SIGMA-COMPLEXES AND PI-COMPLEXES - INTERCONVERSION OF 1-PENTAFLUOROPHENYLTHIO-1,2-DIMETHYL-ACENAPHTHYLENIUM AND 1,2-DIMETHYLACENAPHTHYLENE-1,2-S-PENTAFLUOROPHENYLEPISULPHONIUM IONS Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 1993, Volume: 42, Number: 6, Pages: 1010-1013 Pages count : 4 DOI: 10.1007/BF00704187

Tags

SIGMA-COMPLEXES AND PI-COMPLEXES; EPISULFONIUM IONS; REARRANGEMENT, EQUILIBRIUM; INFLUENCE OF SOLVENT; NMR METHOD

Authors

Borodkin G.I. ¹ , Chernyak E.I. ¹ , Shakirov M.M. ¹ , Shubin V.G. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 8 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

The equilibrium of 1-pentafluorophenylthio-1,2-dimethylacenaphthylenium and 1,2-dimethylacenaphthylene-1,2-S-pentafluorophenylepisulphonium ions in different media has been investigated by H-1 and C-13 NMR spectroscopy using isotope perturbation. It has been found that this equilibrium is weakly sensitive to variation in the medium.

Borodkin G.I. , Chernyak E.I. , Shakirov M.M. , Shubin V.G.
EFFECT OF MEDIUM ON THE EQUILIBRIUM OF CATIONIC SIGMA-COMPLEXES AND PI-COMPLEXES - INTERCONVERSION OF 1-PENTAFLUOROPHENYLTHIO-1,2-DIMETHYL-ACENAPHTHYLENIUM AND 1,2-DIMETHYLACENAPHTHYLENE-1,2-S-PENTAFLUOROPHENYLEPISULPHONIUM IONS
Russian Chemical Bulletin. 1993. V.42. N6. P.1010-1013. DOI: 10.1007/BF00704187 WOS Scopus РИНЦ

Published print:

Jun 1, 1993

Web of science	WOS:A1993NK88500009
Scopus	2-s2.0-34249767038
Elibrary	30894027
OpenAlex	W1974280325