HYDRODECHLORINATION OF CHLORINATED BENZENE AND PHENOLS ON PD-AL2O3 CATALYST Full article
| Journal |
SIBIRSKII KHIMICHESKII ZHURNAL
ISSN: 0134-2428 |
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| Output data | Year: 1992, Number: 6, Pages: 131-134 Pages count : |
| Authors |
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| Affiliations |
Abstract:
The gas phase hydrodechlorination of chlorinated benzens and phenols on Pd/Al2O3 catalyst have been studied at temperatures 353-453 K. Two regions of reaction proceeding were found. At 400 K rate of reaction depends on diffusion of hydrogen. The relative reactivity in hydrodechlorination depends on position of chlorine atom in molecula. The chlorine is firstey removed from the para - and meta - position and more difficult - from orto - position. From the kinetic study follow, that hydrodechlorination of dichlorophenols is consecutive single - step processa: dichlorophenol --> chlorophenol --> phenol --> cyclohe- (sic).
Cite:
Suzdorf A.R.
, Tsiganova S.I.
, Anshits N.N.
, Morozov S.V.
, Anshits A.G.
HYDRODECHLORINATION OF CHLORINATED BENZENE AND PHENOLS ON PD-AL2O3 CATALYST
SIBIRSKII KHIMICHESKII ZHURNAL. 1992. N6. P.131-134. WOS
HYDRODECHLORINATION OF CHLORINATED BENZENE AND PHENOLS ON PD-AL2O3 CATALYST
SIBIRSKII KHIMICHESKII ZHURNAL. 1992. N6. P.131-134. WOS
Identifiers:
| Web of science | WOS:A1992KW60800018 |