Abstract: The complex compounds of Zn2+, Cd2+, Hg2+ with pentafluorothiophenol (HA) and 2,3,5,6-tetrafluoro-4-(trifluoromethyl)-thiophenol (HB) of the formulas MA2 and MB2 have been obtained. Their properties were investigated by means of thermal analysis, X-ray diffraction, vapour phase osmometry and IR-spetroscopy. MA2 and MB2 are monomeric in the acetone solutions. The M-S frequencies are found to lie at 278 (ZnA2), 246 (ZnB2), 239 (CdA2), 227 (CdB2), 225 (HgA2) and 193 cm-1 (HgB2). The Hg2+ complexes are volatile under 4-6.10(-2) Torr pressure and 100-160-degrees-C temperature.

Cite: Larionov S.V. , Kirichenko V.N. , Furin G.G. , Fadeyeva V.P. , Oglezneva I.M. , Lisoivan V.I.
SYNTHESIS AND PROPERTIES OF ZINC(II), CADMIUM(II), MERCURY(II) POLYFLUOROTHIOPHENOLATES
SIBIRSKII KHIMICHESKII ZHURNAL. 1991. N6. P.57-61. WOS

Identifiers:

Web of science

WOS:A1991HF88500009