REARRANGEMENTS OF 1,1A, 6,6A-TETRAHYDROCYCLO-PROP-[A]INDEN-6-OLS IN SUPERACIDS Full article
| Journal |
REVUE ROUMAINE DE CHIMIE
ISSN: 0035-3930 |
|---|---|
| Output data | Year: 1991, Volume: 36, Number: 11-12, Pages: 1307-1313 Pages count : |
| Authors |
|
| Affiliations |
Abstract:
Rearrangements of the methyl substituted 1, la, 6, 6a-tetrahydrocycloprop[a]inden-6-ols (1b-d) in superacids (HSO3F-SO2FCl (A) or HSO3F-SbF5-SO3FCl (B)) are described Carbinols 1c, d rearrange into 4- and 2-methyl-1H-napthalenonium ions, respectively, even at -95-degrees-C, while carbinol 1b gives 6-methyl-1, 1a, 6, 6a-tetrahydrocycloprop[a]inden-6-yl cation (2b) which transforms into 1-methyl-3-fluorosulphonyloxy-methyleneindan-1-yl cation (5) at -25-degrees-C.
Cite:
Razus A.C.
, Bartha E.
, Arvay Z.
, Osadchii S.A.
, Mamatyuk V.I.
, Shubin V.G.
REARRANGEMENTS OF 1,1A, 6,6A-TETRAHYDROCYCLO-PROP-[A]INDEN-6-OLS IN SUPERACIDS
REVUE ROUMAINE DE CHIMIE. 1991. V.36. N11-12. P.1307-1313. WOS
REARRANGEMENTS OF 1,1A, 6,6A-TETRAHYDROCYCLO-PROP-[A]INDEN-6-OLS IN SUPERACIDS
REVUE ROUMAINE DE CHIMIE. 1991. V.36. N11-12. P.1307-1313. WOS
Identifiers:
| Web of science | WOS:A1991HU67200012 |