BEHAVIOR OF 1-HYDROXY-2,2,5,5-TETRAMETHYL-3-IMIDAZOLINE-3-OXIDE AND THE CORRESPONDING NITROXYL RADICALS IN SUPERACID MEDIA

BEHAVIOR OF 1-HYDROXY-2,2,5,5-TETRAMETHYL-3-IMIDAZOLINE-3-OXIDE AND THE CORRESPONDING NITROXYL RADICALS IN SUPERACID MEDIA Full article

Journal

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
ISSN: 0568-5230

Output data

Year: 1991, Volume: 40, Number: 12, Pages: 2399-2404 Pages count : 6 DOI: 10.1007/BF00959709

Authors

Morozov S.V. ¹ , Volodarskii L.B. ¹ , Shubin V.G. ¹

Affiliations

1	Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

The protonation of 1-R-2,2,5,5-tetramethyl-3-imidazoline-3-oxides (R = OH, O) in superacid media was investigated with H-1 and C-13 NMR. The hydroxylamino dication forming on protonation can undergo imidazoline ring opening to form an isomeric mixture of diprotonated N-(2-hydroxyimino-1,1-dimethylethyl), alpha, alpha-dimethylnitrones.

Morozov S.V. , Volodarskii L.B. , Shubin V.G.
BEHAVIOR OF 1-HYDROXY-2,2,5,5-TETRAMETHYL-3-IMIDAZOLINE-3-OXIDE AND THE CORRESPONDING NITROXYL RADICALS IN SUPERACID MEDIA
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1991. V.40. N12. P.2399-2404. DOI: 10.1007/BF00959709 WOS Scopus РИНЦ

Published print:

Dec 1, 1991

Web of science	WOS:A1991JH55200010
Scopus	2-s2.0-34249915843
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