New approach to the generation of aryldifluoroboranes - prospective acid catalysts of organic reactions

New approach to the generation of aryldifluoroboranes - prospective acid catalysts of organic reactions Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2018, Volume: 28, Number: 4, Pages: 369-371 Pages count : 3 DOI: 10.1016/j.mencom.2018.07.009

Authors

Shmakov Mikhail M. ^1,2 , Prikhod'ko Sergey A. ^1,2 , Bardin Vadim V. ^2,3 , Adonin Nicolay Yu ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

A new approach for preparation of aromatic and fluoroaromatic difluoroboranes via the interaction between corresponding aryltrifluoroborates and ionic liquids containing tetrachloroaluminate-anion and aluminum chloride has been developed. Catalytic properties of obtained aryldifluoroboranes have been investigated in model reactions of phenols alkylation. The dependence of catalytic properties on both the nature of solvent used and the type of substituents in the aromatic ring of difluoroborane has been established.

Shmakov M.M. , Prikhod'ko S.A. , Bardin V.V. , Adonin N.Y.
New approach to the generation of aryldifluoroboranes - prospective acid catalysts of organic reactions
Mendeleev Communications. 2018. V.28. N4. P.369-371. DOI: 10.1016/j.mencom.2018.07.009 WOS Scopus РИНЦ

Published print:

Jul 1, 2018

Web of science	WOS:000442709700009
Scopus	2-s2.0-85051020946
Elibrary	35732195
OpenAlex	W2885868937