Tri-p-Tolylbismuth Diperchlorate and mu-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure

Tri-p-Tolylbismuth Diperchlorate and mu-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2018, Volume: 63, Number: 7, Pages: 861-866 Pages count : 6 DOI: 10.1134/S0036023618070069

Authors

Egorova I.V. ¹ , Zhidkov V.V. ¹ , Grinishak I.P. ¹ , Bagryanskaya I.Yu. ^2,3 , Troshina R.S. ¹ , Pervukhina N.V. ⁴

Affiliations

1	(Данные Web of science) Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
4	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

Tri-p-tolylbismuth perchlorate (1) and mu-oxo-bis[(perchlorato)tri-p-tolylbismuth] (2) have been synthesized by the reaction between tri-p-tolylbismuth dibromide and silver perchlorate and its hydrate. The complexes have been studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Complex 1 is triclinic, space group P (1) over bar, Z = 4, a =10.7271(9) angstrom , b = 13.5585(11) angstrom, c = 18.1592(13) angstrom, alpha = 110.867(3) A degrees, beta = 94.944(3)degrees, gamma = 96.888(3)degrees, V = 2426.3(3) angstrom(3), rho(calcd) = 1.865 g/cm(3); complex 2 crystallizes in trigonal symmetry, space group R (3) over bar, a = 13.1157(2) angstrom, c = 22.1959(2) angstrom, gamma = 120 degrees, V = 3306.64(8) angstrom(3), rho(calcd) = 1.777 g/cm(3). The bismuth atoms in the molecular structure of complex 1 have a distorted trigonal bipyramidal coordination to the apically arranged oxygen atoms of perchlorate ions (Bi-C, 2.180(5)-2.201(5) angstrom; Bi-O, 2.324(4)-2.355(4) ; OBiO axial angles, 170.1(1)degrees, 174.5(1)degrees). The structure of complex 2 contains binuclear [p-Tol(3)Bi(ClO4)](2)O molecules (Bi-O, 2.371(15), 1.9107(7) angstrom; OBiO axial angle, 180.0D degrees).

Egorova I.V. , Zhidkov V.V. , Grinishak I.P. , Bagryanskaya I.Y. , Troshina R.S. , Pervukhina N.V.
Tri-p-Tolylbismuth Diperchlorate and mu-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure
Russian Journal of Inorganic Chemistry. 2018. V.63. N7. P.861-866. DOI: 10.1134/S0036023618070069 WOS Scopus РИНЦ

Егорова И.В. , Жидков В.В. , Гринишак И.П. , Багрянская И.Ю. , Трошина Р.С. , Первухина Н.В.
Синтез и строение диперхлората три-n-толилвисмута и μ-оксо-бис[(перхлорато)три-n-толилвисмута]
Журнал неорганической химии. 2018. Т.63. №7. С.816-822. РИНЦ

Published print:	Jul 1, 2018
Published online:	Aug 3, 2018

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