Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5

Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5 Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2018, Volume: 54, Number: 4, Pages: 545-553 Pages count : 9 DOI: 10.1134/S107042801804005X

Authors

Mezhenkova T.V. ¹ , Sinyakov V.R. ¹ , Karpov V.M. ¹ , Zonov Ya.V. ^1,2 , Gatilov Yu.V. ^1,2 , Platonov V.E. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia

The reaction of perfluorobenzocyclobutene with excess pentafluorobenzene in SbF5, followed by hydrolysis, gave a mixture of perfluoro-1,3,3-triphenyl-1,3-dihydro-2-benzofuran-1-ol, perfluoro-1,1,2-triphenylbenzocyclobuten- 5-one, and perfluoro-4-(2,2-diphenylbenzocyclobuten-1-ylidene)cyclohexa-2,5-dien-1- one. When the reaction mixture was treated for a long time with Olah's reagent (HF-pyridine), isomeric perfluoro-9,10-diphenyl-1,4-, -1,10-, -2,9-, and -9,10-dihydroanthracenes were formed and were converted to perfluoro-9,10-diphenylanthracene by the action of SbF5.

Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Zonov Y.V. , Gatilov Y.V. , Platonov V.E.
Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5
Russian Journal of Organic Chemistry. 2018. V.54. N4. P.545-553. DOI: 10.1134/S107042801804005X WOS Scopus РИНЦ

Меженкова Т.В. , Синяков В.Р. , Карпов В.М. , Зонов Я.В. , Гатилов Ю.В. , Платонов В.Е.
Взаимодействие перфторбензоциклобутена с избытком пентафторбензола в sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2018. Т.54. №4. С.546-553. РИНЦ

Published print:	Apr 1, 2018
Published online:	Jun 6, 2018

Web of science	WOS:000434488900005
Scopus	2-s2.0-85048107989
Elibrary	35734610
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