The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series Full article

Journal

ARKIVOC
ISSN: 1551-7004 , E-ISSN: 1551-7012

Output data

Year: 2018, Pages: 359-374 Pages count : 16 DOI: 10.24820/ark.5550190.p010.614

Tags

1,3,5-Triazine-based nitroxides; biradicals; triradicals; organic free radicals; 2,5-dihydroimidazoles

Authors

Zaytseva Elena, V ^1,2 , Gatilov Yury, V ^1,2 , Mazhukin Dmitrii G. ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Acad Lavrenteva Ave, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia

New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and Spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state. [GRAPHICS] .

Zaytseva E.V. , Gatilov Y.V. , Mazhukin D.G.
The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

ARKIVOC. 2018. P.359-374. DOI: 10.24820/ark.5550190.p010.614 WOS Scopus РИНЦ

Full text from publisher

Published online:

Aug 4, 2018

Web of science	WOS:000456008800030
Scopus	2-s2.0-85054570320
Elibrary	38623369
OpenAlex	W2889124283