Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)

Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP) Full article

Journal

Australian Journal of Chemistry
ISSN: 0004-9425 , E-ISSN: 1445-0038

Output data

Year: 2018, Volume: 71, Number: 5, Pages: 334-340 Pages count : 7 DOI: 10.1071/CH17570

Authors

Audran Gerard ¹ , Bagryanskaya Elena ^2,3 , Edeleva Mariya ^2,3 , Marque Sylvain R.A. ^1,2 , Parkhomenko Dmitriy ² , Tretyakov Evgeny ^2,3 , Zhivetyeva Svetlana ²

Affiliations

1	(Данные Web of science) Aix Marseille Univ, ICR, CNRS, UMR 7273, Case 551,Ave Escadrille Normandie Niemen, F-13397 Marseille 20, France
2	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Lavrentjev Ave 9, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia

Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)(2) (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90 degrees C.

Audran G. , Bagryanskaya E. , Edeleva M. , Marque S.R.A. , Parkhomenko D. , Tretyakov E. , Zhivetyeva S.
Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)
Australian Journal of Chemistry. 2018. V.71. N5. P.334-340. DOI: 10.1071/CH17570 WOS Scopus РИНЦ

Web of science	WOS:000432826800003
Scopus	2-s2.0-85047533641
Elibrary	35535498
OpenAlex	W2789153460