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Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization Full article

Journal Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837
Output data Year: 2018, Volume: 87, Number: 4, Pages: 328-349 Pages count : 22 DOI: 10.1070/RCR4765
Authors Edeleva Mariya V. 1,2 , Marque Sylvain 1,3 , Bagryanskaya Elena G. 1,2
Affiliations
1 (Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akademika Lavrentieva 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia
3 (Данные Web of science) Aix Marseille Univ, Natl Ctr Sci Res, Inst Rad Chem Lab 7273, Bldg 551,Ave Escadrille Normandie Niemen, F-13397 Marseille, France

Abstract: Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular -weight distribution. These reactions occur under relatively mild conditions with broad tolerance to functional groups in the monomers. The nitroxide-mediated pseudoliving radical polymerization is of particular interest for the synthesis of polymers for biomedical applications. This review briefly describes one of the mechanisms of controlled radical polymerization. The studies dealing with the use of imidazoline and imidazolidine nitroxides as controlling agents for nitroxide-mediated pseudoliving radical polymerization of various monomers are summarized and analyzed. The publications addressing the key steps of the controlled radical polymerization in the presence of imidazoline and imidazolidine nitroxides and new approaches to nitroxide-mediated polymerization based on protonation of both nitroxides and monomers are considered.
Cite: Edeleva M.V. , Marque S. , Bagryanskaya E.G.
Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization
Russian Chemical Reviews. 2018. V.87. N4. P.328-349. DOI: 10.1070/RCR4765 WOS Scopus
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Еделева М.В. , Марк С.Р. , Багрянская Е.Г.
Имидазолиновые и имидазолидиновые нитроксильные радикалы как регуляторы псевдоживой радикальной полимеризации по механизму обратимого ингибирования
Успехи химии/Uspekhi Khimii. 2018. Т.87. №4. С.328-349. DOI: 10.1070/RCR4765?locatt=label:RUSSIAN РИНЦ
Dates:
Published online: Apr 27, 2018
Published print: Apr 30, 2018
Identifiers:
Web of science WOS:000431973300002
Scopus 2-s2.0-85046547464
OpenAlex W2777358528
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