Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid

Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid Full article

Journal

Chemistry of Natural Compounds
ISSN: 0009-3130 , E-ISSN: 1573-8388

Output data

Year: 2018, Volume: 54, Number: 1, Pages: 46-49 Pages count : 4 DOI: 10.1007/s10600-018-2256-8

Tags

(+)-usnic acid; thioethers; sulfoxidation; chiral oxidation; sulfones

Authors

Sokolov D.N. ¹ , Luzina O.A. ¹ , Salakhutdinov N.F. ^1,2

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Prosp Akad Lavrenteva, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia

Sulfones were produced by meta-chloroperbenzoic-acid oxidation of the corresponding thioethers prepared from (+)-usnic acid. Reaction of the thioethers with H2O2 in the presence of VO(acac)(2) formed a mixture of sulfoxide diastereomers. Possible chiral oxidation of the thioethers into sulfoxides was studied.

Sokolov D.N. , Luzina O.A. , Salakhutdinov N.F.
Synthesis of Sulfones and Sulfoxides Based on (+)-usnic Acid
Chemistry of Natural Compounds. 2018. V.54. N1. P.46-49. DOI: 10.1007/s10600-018-2256-8 WOS Scopus РИНЦ

Published print:	Jan 1, 2018
Published online:	Feb 14, 2018

Web of science	WOS:000425747600012
Scopus	2-s2.0-85042067392
Elibrary	35514988
OpenAlex	W2792666775