Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions

Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2018, Volume: 28, Number: 1, Pages: 27-28 Pages count : 2 DOI: 10.1016/j.mencom.2018.01.007

Authors

Genaev Alexander M. ¹ , Salnikov George E. ^1,2 , Shernyukov Andrey V. ¹ , Zhu Zhongwei ² , Koltunov Konstantin Yu. ^2,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, GK Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

Compared with the parent 1,1'-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C-sp3(1)-C-sp3(1)' bond in its protonated forms.

Genaev A.M. , Salnikov G.E. , Shernyukov A.V. , Zhu Z. , Koltunov K.Y.
Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions
Mendeleev Communications. 2018. V.28. N1. P.27-28. DOI: 10.1016/j.mencom.2018.01.007 WOS Scopus РИНЦ

Published print:

Jan 1, 2018

Web of science	WOS:000425204700007
Scopus	2-s2.0-85041595732
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