Heat-Induced Reactions of 6-Bromo-, 6-Chloro-, and 6-(Methylsulfanyl)octafl uoroindane-5-thiols with Tetrafluoroethylene. Synthesis of Dodecafluoro-2H,3H,5H,6H,7H-indeno[5,6-b]thiophene Full article
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Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Output data | Year: 2019, Volume: 89, Number: 12, Pages: 2378-2385 Pages count : 8 DOI: 10.1134/S1070363219120090 | ||
| Tags | polyfluoroindanethiols; tetrafluoroethylene; co-pyrolysis; dodecafluoro-2H; 3H; 5H; 6H; 7H-indeno[5; 6-b]thiophene | ||
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Abstract:
Dodecafluoro-2H,3H,5H,6H,7H-indeno[5,6-b]thiophene has been synthesized as the major product of co-pyrolysis of 6-bromo-, 6-chlorooctafluoroindane-5-thiols, or bis(6-bromo-5-perfluoroindanyl)disulfane with tetrafluoroethylene under flow conditions at 400-625oC, along with small amount of tetradecafluoro-1,2,3,5,6,7-hexahydro-s-indacene. Dodecafluoro-2H,3H,5H,6H,7H-indeno[5,6-b]thiophene formed in the reaction of 6-(meth-ylsulfanyl)octafluoroindane-5-thiol with tetrafluoroethylene at 420oC has been isolated, and its structure has been confirmed by X-ray diffraction analysis. The schemes of the products formation involving intermediate radicals have been proposed.
Cite:
Nikul'shin P.V.
, Maksimov A.M.
, Gatilov Y.V.
, Platonov V.E.
Heat-Induced Reactions of 6-Bromo-, 6-Chloro-, and 6-(Methylsulfanyl)octafl uoroindane-5-thiols with Tetrafluoroethylene. Synthesis of Dodecafluoro-2H,3H,5H,6H,7H-indeno[5,6-b]thiophene
Russian Journal of General Chemistry. 2019. V.89. N12. P.2378-2385. DOI: 10.1134/S1070363219120090 WOS Scopus РИНЦ
Heat-Induced Reactions of 6-Bromo-, 6-Chloro-, and 6-(Methylsulfanyl)octafl uoroindane-5-thiols with Tetrafluoroethylene. Synthesis of Dodecafluoro-2H,3H,5H,6H,7H-indeno[5,6-b]thiophene
Russian Journal of General Chemistry. 2019. V.89. N12. P.2378-2385. DOI: 10.1134/S1070363219120090 WOS Scopus РИНЦ
ArticleLinkType.TRANSLATED_TO_ORIGINAL:
Никульшин П.В.
, Максимов А.М.
, Гатилов Ю.В.
, Платонов В.Е.
Термические реакции 6-бром-, 6-хлор- и 6-(метилсульфанил)октафториндан-5-тиолов с тетрафторэтиленом. cинтез додекафтор-2H,3H,5H,6H,7H-индено[5,6-b]тиофена
Журнал общей химии (RUSS J GEN CHEM+). 2019. Т.89. №12. С.1859-1868. DOI: 10.1134/S0044460X19120096 РИНЦ
Термические реакции 6-бром-, 6-хлор- и 6-(метилсульфанил)октафториндан-5-тиолов с тетрафторэтиленом. cинтез додекафтор-2H,3H,5H,6H,7H-индено[5,6-b]тиофена
Журнал общей химии (RUSS J GEN CHEM+). 2019. Т.89. №12. С.1859-1868. DOI: 10.1134/S0044460X19120096 РИНЦ
Dates:
| Submitted: | May 20, 2019 |
| Accepted: | May 25, 2019 |
| Published print: | Feb 26, 2020 |
| Published online: | Feb 26, 2020 |
Identifiers:
| Web of science | WOS:000515000800009 |
| Scopus | 2-s2.0-85079689391 |
| Elibrary | 43248374 |
| OpenAlex | W3006723647 |