The first isolation of lithium perfluoroorganotrimethoxyborates Li [RFB(OMe)3] (RF = C2F5, CF2=CF and C6F5) - three samples of new classes of fluoroorganoboron compounds

The first isolation of lithium perfluoroorganotrimethoxyborates Li [RFB(OMe)3] (RF = C2F5, CF2=CF and C6F5) - three samples of new classes of fluoroorganoboron compounds Full article

Journal

Main Group Metal Chemistry
ISSN: 0792-1241

Output data

Year: 2001, Volume: 24, Number: 12, Pages: 845-846 Pages count : 2 DOI: 10.1515/MGMC.2001.24.12.845

Authors

Frohn Hermann-Josef ¹ , Adonin Nicolay Yu. ² , Bardin Vadim V. ²

Affiliations

1	(Scopus) Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universit?t Duisburg, Lotharstr. 1, 2 D-47048 Duisburg, Germany
2	(Scopus) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, 630090 Novosibirsk, Russian Federation

The previously unknown classes of fluoroorganoboron compounds, lithium perfluoroorganotrimethoxyborates Li [RFB(OCH3)3] (RF = C2F5, CF2=CF and C6F5), were prepared by the nucleophilic addition of RFLi to B(OCH3)3 in ether. The Li [RFB(OCH3)3] salts contain no ether coordinated at Li+ and are stable at room temperature towards elimination. In solution they show a differentiated behaviour of protodeborylation.

Frohn H-J. , Adonin N.Y. , Bardin V.V.
The first isolation of lithium perfluoroorganotrimethoxyborates Li [RFB(OMe)3] (RF = C2F5, CF2=CF and C6F5) - three samples of new classes of fluoroorganoboron compounds
Main Group Metal Chemistry. 2001. V.24. N12. P.845-846. DOI: 10.1515/MGMC.2001.24.12.845 WOS Scopus РИНЦ

Published print:

Jan 1, 2001

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