One-pot synthesis of {Mo6I8}(4+)-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

One-pot synthesis of {Mo6I8}(4+)-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction Full article

Journal

Polymer International
ISSN: 0959-8103 , E-ISSN: 1097-0126

Output data

Year: 2017, Volume: 66, Number: 12, Pages: 1906-1912 Pages count : 7 DOI: 10.1002/pi.5473

Tags

molybdenum cluster complex; free radical polymerisation; copolymer material; luminescence

Authors

Vorotnikova Natalya A. ² , Edeleva Mariya V. ^3,4 , Kurskaya Olga G. ⁵ , Brylev Konstantin A. ^2,4 , Shestopalov Alexander M. ⁵ , Mironov Yuri V. ^2,4 , Sutherland Andrew J. ⁶ , Efremova Olga A. ¹ , Shestopalov Michael A. ^2,4,5

Affiliations

1	(Данные Web of science) Univ Hull, Sch Math & Phys Sci, Kingston Upon Hull HU6 7RX, N Humberside, England
2	(Данные Web of science) RAS, SB, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) RAS, SB, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia
4	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia
5	(Данные Web of science) Res Inst Expt & Clin Med, Novosibirsk, Russia
6	(Данные Web of science) Aston Univ, Aston Inst Mat Res, Birmingham, W Midlands, England

Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [{Mo6X8}(NO3)(6)](2-) (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated. (c) 2017 Society of Chemical Industry

Vorotnikova N.A. , Edeleva M.V. , Kurskaya O.G. , Brylev K.A. , Shestopalov A.M. , Mironov Y.V. , Sutherland A.J. , Efremova O.A. , Shestopalov M.A.
One-pot synthesis of {Mo6I8}(4+)-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

Polymer International. 2017. V.66. N12. P.1906-1912. DOI: 10.1002/pi.5473 WOS Scopus

Full text from publisher

Published online:	Oct 18, 2017
Published print:	Dec 1, 2017

Web of science	WOS:000415357400025
Scopus	2-s2.0-85031678536
OpenAlex	W2760745963