Equilibrating system of 2-methylbenzonorbornen-2-yl type cations

Equilibrating system of 2-methylbenzonorbornen-2-yl type cations Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 1996, Volume: 6, Number: 5, Pages: 187-189 Pages count : 3 DOI: 10.1070/MC1996v006n05ABEH000610

Authors

Bushmelev V.A. ¹ , Vetchinov V.P. ¹ , Genaev A.M. ¹ , Mamatyuk V.I. ¹ , Shubin V.G. ¹

Affiliations

1	(Scopus) Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

The nature of the changes in the 13C NMR spectra of the 2-methylbenzonorbornen-2-yl carbocation caused by the substitution of deuterium for hydrogen in the methyl group and by temperature variation suggests that in fact this cation represents a system of two or more species with differing extents of π-bridging separated by a very low energy barrier.

Bushmelev V.A. , Vetchinov V.P. , Genaev A.M. , Mamatyuk V.I. , Shubin V.G.
Equilibrating system of 2-methylbenzonorbornen-2-yl type cations
Mendeleev Communications. 1996. V.6. N5. P.187-189. DOI: 10.1070/MC1996v006n05ABEH000610 WOS Scopus РИНЦ

Published print:

Jan 1, 1996

Web of science	WOS:A1996VM79000009
Scopus	2-s2.0-0001772274
Elibrary	13222391
OpenAlex	W2003377223