Gas phase hydrodechlorination of chlorinated aromatic compounds on nickel catalysts

Gas phase hydrodechlorination of chlorinated aromatic compounds on nickel catalysts Full article

Journal

Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X

Output data

Year: 1994, Volume: 29, Number: 1-2, Pages: 49-55 Pages count : DOI: 10.1007/BF00814251

Tags

hydrodechlorination; Ni/γ-Al2O3 catalysts; substituted chlorobenzene

Authors

Suzdorf A. R. , Morozov S. V. , Anshits N. N. , Tsiganova S. I. , Anshits A. G.

Affiliations

1	(Scopus) Institute of Chemistry of Natural Organic Materials, K. Marx St. 42, Krasnoyarsk, 660049, Russian Federation
2	(Scopus) Institute of Organic Chemistry, Lavrent'ev Av. 7, Novosibirsk, 630090, Russian Federation

Supported Ni/γ-Al2O3 catalysts were studied in the gas phase hydrodechlorination of substituted chlorobenzenes. The catalytic properties of the catalysts were shown to be determined by the metal nickel. A correlation between the rate of the gas phase hydrodechlorination of substituted chlorobenzene and donor-acceptor properties of substituents was established. The electron-donor substituents increase and the electron-acceptor ones decrease their reactivity. The correlation analysis of data treated via the Hammett equation shows that hydrodechlorination on Ni/γ-Al2O3 catalysts is a reaction of electrophilic type. © 1994 J.C. Baltzer AG, Science Publishers.

Suzdorf A.R. , Morozov S.V. , Anshits N.N. , Tsiganova S.I. , Anshits A.G.
Gas phase hydrodechlorination of chlorinated aromatic compounds on nickel catalysts
Catalysis Letters. 1994. V.29. N1-2. P.49-55. DOI: 10.1007/BF00814251 WOS Scopus

Web of science	WOS:A1994PR85400007
Scopus	2-s2.0-0002427094
OpenAlex	W1972228332