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Emission tuning in Re(I) complexes: Expanding heterocyclic ligands and/or introduction of perfluorinated ligands Full article

Journal Polyhedron
ISSN: 0277-5387
Output data Year: 2017, Volume: 137, Pages: 231-237 Pages count : DOI: 10.1016/j.poly.2017.08.046
Tags Rhenium; Diimine; Luminescence; Perfluorinated ligands
Authors Abramov Pavel A. 1,2 , Brylev Konstantin A. 1,2 , Vorob'ev Aleksei Yu. 2,3 , Gatilov Yuriy V. 2,3 , Borodkin Gennadiy I. 2,3 , Kitamura Noboru 4 , Sokolov Maxim N. 1,2,5
Affiliations
1 (Данные Web of science) Nikolaev Inst Inorgan Chem, 3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
3 (Данные Web of science) Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
4 (Данные Web of science) Hokkaido Univ, Dept Chem, Fac Sci, Sapporo, Hokkaido 0600810, Japan
5 (Данные Web of science) Kazan Fed Univ, Kremlyovskaya St 18, Kazan 420008, Russia

Abstract: Reactions of new heterocyclic ligands 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a]quinolin-9-ol (L-OH), 2-(pyridin-2-yl)-[1,2,4]triazolo[1,5-a][1,10]phenanthroline (L-Py) and 2-methyl-[1,2,4]triazolo[1,5-a][1,10] phenanthroline (L-Me) with [Re(CO)(5)Br] in toluene afforded the complexes of the general formula [(L) Re(CO)(3)Br]. Substitution of the Br- ligand in [(L)Re(CO)(3)Br] by C3F7COO- leads to [(L)Re (CO)(3)(OOCC3F7)] and results in increased emission lifetime. (C) 2017 Elsevier Ltd. All rights reserved.
Cite: Abramov P.A. , Brylev K.A. , Vorob'ev A.Y. , Gatilov Y.V. , Borodkin G.I. , Kitamura N. , Sokolov M.N.
Emission tuning in Re(I) complexes: Expanding heterocyclic ligands and/or introduction of perfluorinated ligands
Polyhedron. 2017. V.137. P.231-237. DOI: 10.1016/j.poly.2017.08.046 WOS Scopus
Dates:
Published print: Nov 1, 2017
Identifiers:
Web of science WOS:000414881700028
Scopus 2-s2.0-85029307470
OpenAlex W2753399588
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