Skeletal Rearrangements of Perfluorinated Ethyl-and Diethyltetralins by the Action of Antimony Fluoride

Skeletal Rearrangements of Perfluorinated Ethyl-and Diethyltetralins by the Action of Antimony Fluoride Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1997, Volume: 33, Number: 5, Pages: 694-699 Pages count : 6

Authors

Karpov V.M. ¹ , Mezhenkova T.V. ¹ , Platonov V.E. ¹

Affiliations

1	(Scopus) Novosibirsk Inst. of Organ. Chem., Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russian Federation

On treatment with SbF5 at 130°C perfluoro(1-ethyltetralin) undergoes isomerization into perfluoro-(5-ethyltetralin); contraction of the saturated ring in the latter yields perfluoro(7-ethyl-1-methylindan). Reaction of perfluoro(1-ethyltetralin) with SbF5 under more severe conditions (170-200°C) yield perfluoro(1,3,4-trimethylindan). Perfluoro(1,4-diethyltetralin) reacts with SbF5 at 130°C to give a mixture of perfluorinated 5,8-diethyltetralin, 4,7-diethyl-1-methylindan, and 3,6-diethyl-1,1-dimethylbenzocyclobutene.

Karpov V.M. , Mezhenkova T.V. , Platonov V.E.
Skeletal Rearrangements of Perfluorinated Ethyl-and Diethyltetralins by the Action of Antimony Fluoride
Russian Journal of Organic Chemistry. 1997. V.33. N5. P.694-699. Scopus РИНЦ

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