[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy

[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2017, Volume: 2017, Number: 36, Pages: 5410-5416 Pages count : 7 DOI: 10.1002/ejoc.201700946

Tags

Aromaticity; Cyclophanes; N-Methylpyridinium salts; Nitropyridines; Rearrangement

Authors

Shuvalov Vladislav Yu. ¹ , Eltsov Ilia V. ² , Tumanov Nikolay A. ^2,4 , Boldyreva Elena V. ² , Nefedov Andrey A. ³ , Sagitullina Galina P. ¹

Affiliations

1	(Данные Web of science) FM Dostoevsky Omsk State Univ, Dept Organ Chem, Omsk 644077, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
4	(Данные Web of science) Univ Namur, Dept Chem, Rue Bruxelles 61, B-5000 Namur, Belgium

Metacyclophanes have been developed as non-planar aromatic compounds with unusual physical properties. [6]-[9]Metacyclophanes were synthesized by rearrangement of 3-nitro(perhydrocycloalka)[b]pyridinium salts, and analysis of their spectroscopic data and X-ray diffraction patterns indicates the aromaticity and flexibility of their benzene rings. The effectiveness and simplicity of the synthesis makes it possible to use them as available precursors in the synthesis of retinoids, indolophanes, and carbazolophanes.

Shuvalov V.Y. , Eltsov I.V. , Tumanov N.A. , Boldyreva E.V. , Nefedov A.A. , Sagitullina G.P.
[6]-[9]Metacyclophanes: Synthesis, Crystal Structures, and NMR and UV Spectroscopy
European Journal of Organic Chemistry. 2017. V.2017. N36. P.5410-5416. DOI: 10.1002/ejoc.201700946 WOS Scopus РИНЦ

Published online:	Sep 29, 2017
Published print:	Oct 2, 2017

Web of science	WOS:000412127100006
Scopus	2-s2.0-85030169118
Elibrary	31051478
OpenAlex	W2742255552