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Complexes with nitroxides containing different substituents in the α-position to N·-O group competition of basicity and sterical availability of the donor functions of nitroxides in metal complexes with sterically hindered imidazolines Full article

Journal Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
ISSN: 1058-725X
Output data Year: 1997, Volume: 305, Pages: 311-320 Pages count : 10 DOI: 10.1080/10587259708045068
Authors Ovcharenko V. 1 , Korobkov I. 1 , Fokin S. 1 , Burdukov A. 1 , Romanenko G. 2 , Ikorskii V. 1 , Pervukhina N. 1 , Mazhukin D. 3 , Rezntkov V. 3
Affiliations
1 (Scopus) International Tomography Center, Rus. Acad. Sci., 630090 Novosibirsk, Russian Federation
2 (Scopus) Institute of Inorganic Chemistry, Rus. Acad. Sci., 630090 Novosibirsk, Russian Federation
3 (Scopus) Institute of Organic Chemistry, Rus. Acad. Sci., 630090 Novosibirsk, Russian Federation

Abstract: In the nitroxide molecule, change of the substituent in the α-position to the N·-O group affects both the donor properties of this group and its steric availability Metal complexes with three nitroxide pairs are used to show that the above change of the α-substituent in the nitroxide molecule can induce structural transformation of the molecular complex itself (and, as a consequence, change its magnetic properties), change the magnetic properties of the solid complex, or change the chemical behavior of the nitroxide.
Cite: Ovcharenko V. , Korobkov I. , Fokin S. , Burdukov A. , Romanenko G. , Ikorskii V. , Pervukhina N. , Mazhukin D. , Rezntkov V.
Complexes with nitroxides containing different substituents in the α-position to N·-O group competition of basicity and sterical availability of the donor functions of nitroxides in metal complexes with sterically hindered imidazolines
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 1997. V.305. P.311-320. DOI: 10.1080/10587259708045068 WOS Scopus
Dates:
Published print: Oct 1, 1997
Published online: Oct 4, 2006
Identifiers:
Web of science WOS:A1997YF19100027
Scopus 2-s2.0-0031341535
OpenAlex W2043131561
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