Skeletal transformations and fluorination of perfluoroalkylbenzenes in reactions with antimony pentafluoride

Skeletal transformations and fluorination of perfluoroalkylbenzenes in reactions with antimony pentafluoride Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 1999, Volume: 35, Number: 8, Pages: 1176-1181 Pages count : 6

Authors

Karpov V.M. , Mezhenkova T.V. , Platonov V.E.

Affiliations

1	(Scopus) Vorozhtsov Novosibirsk Inst. of O., Siberian Division, Russian Academy of Sciences, Novosibirsk, 639090, Russian Federation

Reaction of octafluorotoluene and perfluoro-m-xylene with tetrafluoroethylene in the presence of SbF5 yielded perfluorinated propyl-and 1,3-dipropylbenzene, and propyltoluene. The perfluoropropyl group of these compounds under the action of SbF5 at 200°C is transformed into perfluoroisopropyl or trifluoromethyl group. Polyfluoroalkylbenzenes in SbF5 medium undergo fluorinationb to afford perfluoro1-alkylcyclohexenes.

Karpov V.M. , Mezhenkova T.V. , Platonov V.E.
Skeletal transformations and fluorination of perfluoroalkylbenzenes in reactions with antimony pentafluoride
Russian Journal of Organic Chemistry. 1999. V.35. N8. P.1176-1181. Scopus РИНЦ

Scopus	2-s2.0-0033233754
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