Synthesis and properties of nickel(II) and cobalt(II) complexes with a chiral dioxatetraazamacrocyclic ligand (L) based on a natural monoterpene, (+)-3-carene: The crystal structure of [NiL](NO3)2

Synthesis and properties of nickel(II) and cobalt(II) complexes with a chiral dioxatetraazamacrocyclic ligand (L) based on a natural monoterpene, (+)-3-carene: The crystal structure of [NiL](NO3)2 Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2005, Volume: 50, Number: 4, Pages: 521-526 Pages count : 6

Authors

Larionov S.V. ¹ , Myachina L.I. ¹ , Klevtsova R.F. ¹ , Glinskaya L.A. ¹ , Sheludyakova L.A. ¹ , Bizyaev S.N. ² , Tkachev A.V. ²

Affiliations

1	(Scopus) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russian Federation
2	(Scopus) Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation

The diamagnetic complexes [NiL](NO3)2 (I) and [NiL](ClO4)2·2H2O (II) and paramagnetic complex CoL(NO3)2·H2O (III), where L is an optically active dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene, were synthesized. According to X-ray diffraction, the structure of I is ionic. In the complex cation, the NiN4 coordination core is a tetrahedrally distorted square formed through coordination of the tetradentate ring-forming ligand L. Complex II contains a similar coordination core. According to the data of UV and IR spectroscopy, the Co coordination polyhedron in III is a N4O2 octahedron. Copyright © 2005 by Pleiades Publishing, Inc.

Larionov S.V. , Myachina L.I. , Klevtsova R.F. , Glinskaya L.A. , Sheludyakova L.A. , Bizyaev S.N. , Tkachev A.V.
Synthesis and properties of nickel(II) and cobalt(II) complexes with a chiral dioxatetraazamacrocyclic ligand (L) based on a natural monoterpene, (+)-3-carene: The crystal structure of [NiL](NO3)2
Russian Journal of Inorganic Chemistry. 2005. V.50. N4. P.521-526. WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Клевцова Р.Ф. , Глинская Л.А. , Шелудякова Л.А. , Бизяев С.Н. , Ткачев А.В.
СИНТЕЗ И СВОЙСТВА КОМПЛЕКСОВ НИКЕЛЯ(II) И КОБАЛЬТА(II) С ХИРАЛЬНЫМ ДИОКСАТЕТРААЗАМАКРОЦИКЛИЧЕСКИМ ЛИГАНДОМ (L) НА ОСНОВЕ ПРИРОДНОГО МОНОТЕРПЕНА(+)-3-КАРЕНА. КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА КОМПЛЕКСА [NIL](N03)2
Журнал неорганической химии. 2005. Т.50. №4. С.582-588. РИНЦ

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